Chemistry of the Environment

by ;
Edition: 2nd
Format: Paperback
Pub. Date: 2003-01-01
Publisher(s): Pearson College Div
List Price: $134.17

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Summary

Concise, comprehensive, readable, and current, Chemistry of the Environment, Second EDITION, is the most thorough, up-to-date, and user-friENDly treatment of environmental chemistry available. This book, designed for students who have taken or are taking general chemistry, explores and discusses topics such as energy flow through nature, the greenhouse effect, climate modeling, chemistry of the ozone layer, air pollution, redox potential and water pollution, toxic chemicals, and acid rain. Featuring an unsurpassed marriage of chemical principles with issues of environmental concern, this book is unrivaled in terms of its ability to explain the chemistry behind the headlines.

Author Biography

Thomas G. Spiro is a Professor of Chemistry at Princeton University and has taught environmental chemistry there since 1970.

Table of Contents

Preface xi
Introduction xiii
Part I Energy 1(142)
Energy Flows and Supplies
3(16)
Prologue on Energy and Sustainability
3(2)
Natural Energy Flows
5(3)
Human Energy Consumption
8(6)
Human Energy Sources
14(5)
Fossil Fuels
19(25)
Carbon Cycle
19(2)
Origins of Fossil Fuels
21(4)
Fuel Energy
25(4)
Petroleum
29(8)
Composition and Refining
29(2)
Advantages
31(1)
Disadvantages
31(6)
Gas
37(1)
Advantages
38(1)
Disadvantages
38(1)
Coal
38(4)
Advantages
39(1)
Disadvantages
39(3)
Decarbonization
42(2)
Separation
42(1)
Storage
42(2)
Nuclear Energy
44(30)
Nuclei, Isotopes, and Radioactivity
44(3)
Naturally Occurring Radioisotopes
47(2)
Decay Chains: The Radon Problem
49(1)
Radioactivity: Biological Effects of Ionizing Radiation
50(3)
Alpha Rays
52(1)
Beta and Gamma Rays, and Neutrons
52(1)
Radiation Exposure
53(1)
Fission
54(6)
Pressurized Light-Water Reactor
56(1)
Isotope Separation
57(1)
Breeder Reactor
58(2)
Reprocessing
60(1)
Hazards of Nuclear Power
60(7)
Reactor Safety: Three Mile Island and Chernobyl
60(3)
Weapons Proliferation
63(2)
Nuclear Waste Disposal
65(2)
Nuclear Power Part of the Future?
67(1)
Fusion
68(6)
Fusion Reactions
68(2)
Fusion Power Reactors
70(3)
Is Fusion the Energy Source of the Future?
73(1)
Renewable Energy
74(24)
Solar Heating
77(2)
Solar Thermal Electricity
79(1)
Photovoltaic Electricity
80(7)
Principles of the PV Cell
81(4)
Photosynthesis and Photoelectrochemistry
85(2)
Biomass
87(4)
Ethanol from Biomass
88(2)
Methane from Biomass
90(1)
Hydroelectricity
91(1)
Wind Power
92(3)
Ocean Energy
95(1)
Geothermal Energy
96(2)
Energy Utilization
98(45)
Heat Engine Efficiencies
100(3)
Fuel Cells
103(6)
Space Heating, Cogeneration
109(1)
Electricity Storage: The Hydrogen Economy
109(3)
The Materials Connection
112(7)
Materials Properties: Paper versus Plastics
113(1)
Recycling
113(4)
Dematerialization
117(2)
Systems Efficiency
119(10)
Transportation
120(5)
Industrial Ecology
125(3)
Green Chemistry
128(1)
Energy and Society
129(14)
Summary
133(1)
Problem Set
134(5)
Suggested Readings
139(4)
Part II Atmosphere 143(108)
Climate
145(35)
Radiation Balance
145(5)
Albedo: Particles and Clouds
150(10)
Clouds
150(3)
Aerosol Particles
153(3)
Sulfur Cycle
156(4)
Greenhouse Effect
160(12)
Infrared Absorption and Molecular Vibrations
160(5)
Greenhouse Gas Trends
165(7)
Climate Modeling
172(6)
International Agreements on Greenhouse Gases
178(2)
Oxygen Chemistry
180(14)
Nitrogen Oxides: Free Energy
180(5)
Free Energy and the Equilibrium Constant
181(2)
Free Energy and Temperature
183(2)
Nitrogen Oxides: Kinetics
185(1)
Free Radical Chain Reactions
186(8)
Oxygen Radicals
187(3)
Organic Oxygen Radicals
190(1)
Hydroxyl Radical
191(1)
Transition Metal Activation of OZ
192(2)
Stratospheric Ozone
194(22)
Atmospheric Structure
196(4)
Ultraviolet Protection by Ozone
200(3)
Ozone Chemistry
203(4)
Formation and Destruction
203(1)
Calculating the Ozone Steady State
204(3)
Catalytic Destruction of Ozone
207(2)
Hydroxyl Radical
207(1)
Chlorine and Bromine
207(1)
Nitric Oxide
208(1)
Polar Ozone Destruction
209(4)
Ozone Projections
213(1)
CFC Subsititutes
213(3)
Air Pollution
216(35)
Pollutants and Their Effects
216(11)
Carbon Monoxide
216(2)
Sulfur Dioxide
218(2)
Toxic Organics
220(2)
Particles
222(1)
NOx and Volatile Organics
223(3)
Ozone and Other Oxidants
226(1)
Photochemical Smog
227(5)
Emission Control
232(5)
Sulfur Dioxide
232(1)
Nitrogen Oxides, Carbon Monoxide, and Hydrocarbons
233(4)
Reformulated Gasoline: Oxygenates
237(14)
Knocking and Octane
237(1)
Diesels and Cetane
238(1)
Lead in Gasoline
238(1)
Reformulated Gasoline
239(2)
Summary
241(1)
Problem Set
242(5)
Suggested Readings
247(4)
Part III Hydrosphere/Lithosphere 251(104)
Water Resources
253(13)
Global Perspective
253(3)
Irrigation
256(3)
Groundwater
259(1)
U.S. Water Resources
260(2)
The Oceans
262(3)
Water as Solvent and as a Biological Medium
265(1)
From Clouds to Runoff: Water as Solvent
266(16)
Unique Properties of Water
266(6)
Hydrogen Bonding
266(3)
Clathrates and Water Miscibility
269(3)
Acids, Bases, and Salts
272(4)
Ions, Autoionization, and pH
272(2)
Weak Acids and Bases
274(2)
Conjugate Acids and Bases; Buffers
276(1)
Water in the Atmosphere: Acid Rain
277(5)
Water and the Lithosphere
282(25)
Earth as Acid-Base Reactor
282(2)
Organic and Inorganic Carbon Cycles
284(5)
The Carbonate Control
286(2)
Carbonate Sequestration
288(1)
Weathering and Solubilization Mechanisms
289(8)
Ionic Solids and the Solubility Product
289(1)
Solubility and Basicity
290(2)
Ion Exchange; Clays and Humic Substances
292(5)
Effects of Acidification
297(10)
Soil Neutralization
297(1)
Hardness and Detergents
298(2)
Acid Deposition and Watershed Buffering
300(3)
Ecosystem Effects of Acid Rain
303(2)
Acid Mine Drainage
305(1)
Global Acidification
305(2)
Oxygen and Life
307(26)
Redox Reactions and Energy
307(9)
Biological Oxygen Demand
309(2)
Natural Sequence of Biological Reductions
311(4)
Biological Oxidations
315(1)
Aerobic Earth
316(3)
Water as Ecological Medium
319(14)
The Euphotic Zone and the Biological Pump
319(1)
Eutrophication in Freshwater Lakes
319(4)
Nitrogen and Phosphorus: The Limiting Nutrients
323(2)
Anoxia and its Effects on Coastal Marine Waters
325(3)
Wetlands as Chemical Sinks
328(2)
Redox Effects on Metals Pollution
330(1)
Fertilizing the Ocean with Iron
331(2)
Water Pollution and Water treatment
333(22)
Water Use and Water Quality: Point and Nonpoint Sources of Pollution
333(4)
Regulation of Water Quality
337(2)
Water and Sewage Treatment
339(2)
Health Hazards
341(14)
Pathogens and Disinfection
341(3)
Organic and Inorganic Contaminants
344(2)
Summary
346(1)
Problem Set
347(4)
Suggested Readings
351(4)
Part IV Biosphere 355(106)
Nitrogen and Food Production
357(25)
Nitrogen Cycle
357(4)
Agriculture
361(7)
Fertilizer and the Green Revolution
361(6)
Environmental Degradation
367(1)
Nutrition
368(14)
Energy and Calories
369(1)
Protein
370(4)
Minerals and Vitamins
374(1)
Antioxidants
375(7)
Pest Control
382(25)
Insecticides
382(15)
Persistent Insecticides: Organochlorines
382(4)
Ecosystem Effects; Bioaccumulation
386(4)
Nonpersistent Insecticides: Organophosphates and Carbamates
390(4)
Natural Insecticides
394(1)
Integrated Pest Management
394(3)
Herbicides
397(4)
Genetically Modified Organisms (GMOs)
401(6)
GM Plants: Actualities and Potential
401(1)
Resistance to GM Foods
402(5)
Toxic Chemicals
407(54)
Acute and Chronic Toxicity
407(3)
Cancer
410(8)
Mechanisms
411(4)
Cancer Incidence and Testing
415(3)
Hormonal Effects
418(5)
Persistent Organic Pollutants: Dioxins and PCBs
423(9)
Dioxins and Furans
423(6)
Polychlorinated Biphenyls
429(3)
Global Transport
432(1)
Toxic Metals
432(29)
Summary
452(2)
Problem Set
454(4)
Suggested Readings
458(3)
Appendix Organic Structures 461(10)
Hydrocarbons; Alkanes
461(1)
Branched Chains; Isomers
462(1)
Rings
463(1)
Unsaturated Hydrocarbons
464(1)
Molecular Shape
465(1)
Carbon Framework Representations
465(1)
Aromatic Compounds
466(1)
Hetero-Atoms; Functional Groups
467(4)
Index 471

Excerpts

This book is about environmental issues and the chemistry behind them. It is not a methods book, nor is it a catalog of pollutants and remediation options. It aims to deepen knowledge of chemistry and of the environment and to show the power of chemistry as a tool to help us comprehend the changing world around us. In the six years since the first edition ofChemistry of the Environmentwas published, the frontiers of environmental science have advanced rapidly, and the debates on environmental issues have shifted ground. In this new edition, we have updated the various strands of our environmental story by integrating new facts and figures in the text, tables, and diagrams. Recognizing that no book on environmental themes can stay current for long, we plan to post further updates on our website http://www.prenhall.com/spiro2 . Some of the new material e.g., ocean chemistry and the inorganic carbon cycle (pp. 284-288), or the evolution of the oxygen atmosphere (pp. 316-319) might have been included earlier, but some topics had not surfaced six years ago. These include genetically modified crops (pp. 401-406), carbon sequestration as a strategy for reducing greenhouse gas emissions (pp. 423, 288), and contamination of drinking water by the gasoline additive MTBE (pp. 260, 271, 344). Chemistry of the Environmentcan be used in a one- or two-term environmental chemistry course. The instructor in a one-term course will want to pick a limited set of the book's topics for special emphasis; in a two-term course there would be time to address other topics and to explore the underlying chemical principles in more detail. The new edition is also suitable for basic environmental science courses. Readers will find that the biggest change from the first edition is improved accessibility through reorganization and expansion of the basic chemistry. We have separated background material relevant to the understanding of the topic under discussion into boxes marked Fundamentals. We have also added additional basic material, to help those readers without exposure to college chemistry, and to refresh the memories of those who have had such exposure. In addition, we have included worked problems in other boxes, and have added more end-of-chapter problems. A periodic table is now included, as is an Appendix that gives a brief introduction to organic chemical structures. Some of the Fundamentals boxes contain non-chemical background information e.g., how to relate reservoirs and flows in environmental chemical cycles, p. 285-286. In addition, we have separated the more advanced or specialized technical information into other boxes called Strategies, which readers can read or skip at their discretion. In this way, the environmental story line is unimpeded by background or technical information. We hope that these changes will make the book easier to read, and also more useful as a textbook. We are indebted to a number of colleagues for reviewing parts of the manuscript, and/or providing new material: Drs. Michael Bender, Andrew Bocarsly, Harold Feiveson, Robert Goldston, Peter Jaffe, Hiram Levy, Francois Morel, Steve Pacala, Lynn Russel, Jorge Sarmiento, Daniel Sigman, Robert Socolow, Valerie Thomas (all from Princeton University); Trace Jordan (New York University); Bibudhendra Sarkar (University of Toronto); David Walker (University of British Columbia); and Chris Weber (student assistant, University of Iowa). Helen Spiro provided encouragement throughout the writing, and key editorial advice. Thanks also to Marie Stigliani--her companionship on bicycle trails along the Cedar River provided balance to long days at the office. Supplements Instructor's Solutions Manual--(0-13-017843-8) Contains the full solution to all end-of-chapter problems and is available to instructors upon adoption. Companion Website-

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