Functional Organic Materials Syntheses, Strategies and Applications
by Mü; ller, Thomas J. J.; Bunz, Uwe H. F.Edition: 1st
Format: Hardcover
Pub. Date: 2007-02-12
Publisher(s): Wiley-VCH
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Summary
This timely overview of the syntheses for functional pi-systems focuses on target molecules that have shown interesting properties as materials or models in physics, biology and chemistry. The unique concept allows readers to select the right synthetic strategy for success, making it invaluable for a number of industrial applications. A "must have" for everyone working in this new and rapidly expanding field.
Author Biography
Thomas J. J. Müeller is currently professor at the university of Düsseldorf. He is interested in the synthetic, methodological and physical chemical development of heterocyclic chemistry and its implications in medicinal chemistry, materials science and nanotechnology.
Uwe H. F. Bunz is professor at the Georgia Institute of Technology, Atlanta working on alkyne chemistry, polymer chemistry, chemistry of carbon rich materials, sugar and carbohydrate chemistry.
Table of Contents
| Preface | |
| List of Contributors | |
| 3-D Carbon-rich ¿-Systems – Nanotubes and Segments | |
| Functionalization of Carbon Nanotubes | |
| Introduction to Carbon Nanotubes – A New Carbon Allotrope | |
| Functionalization of Carbon Nanotubes | |
| Covalent Functionalization | |
| Noncovalent Exohedral Functionalization–Functionalization with Biomolecules | |
| Endohedral Functionalization | |
| Conclusions | |
| Experimental | |
| Cyclophenacene Cut Out of Fullerene | |
| Introduction | |
| Synthesis of [10]Cyclophenacene ¿-Conjugated Systems from [60]Fullerene | |
| Conclusion | |
| Experimental | |
| Strategic Advances in Chromophore and Materials Synthesis | |
| Cruciform ¿-Conjugated Oligomers | |
| Introduction | |
| Oligomers with a Tetrahedral Core Unit | |
| Oligomers with a Tetrasubstituted Benzene Core | |
| Oligomers with a Tetrasubstituted Biaryl Core | |
| Conclusion | |
| Experimental | |
| Design of ¿-Conjugated Systems Using Organophosphorus Building Blocks | |
| Introduction | |
| Phosphole-containing ¿-Conjugated Systems | |
| Phosphine-containing ¿-Conjugated Systems | |
| Phosphaalkene- and Diphosphene-containing ¿jugated Systems | |
| Conclusion | |
| Selected Experimental Procedures | |
| Diversity-oriented Synthesis of Chromophores by Combinatorial Strategies and Multi-component Reactions | |
| Introduction | |
| Combinatorial Syntheses of Chromophores | |
| Novel Multi-component Syntheses of Chromophores | |
| Conclusion and Outlook | |
| Experimental Procedures | |
| High-yield Synthesis of Shape-persistent Phenylene–Ethynylene Macrocycles | |
| Introduction | |
| Synthesis | |
| Conclusion | |
| Experimental Procedures | |
| Functional Materials via Multiple Noncovalent Interactions | |
| Introduction | |
| Biologically Inspired Materials via Multi-step Self-assembly | |
| Small Molecule-based Multi-step Self-assembly | |
| Polymer-based Self-assembly | |
| Conclusion and Outlook | |
| Molecular Muscles, Switches and Electronics | |
| Molecular Motors and Muscles | |
| Introduction | |
| Mechanically Interlocked Molecules as Artificial Molecular Machines | |
| Chemically Induced Switching of the Bistable Rotaxanes | |
| Electrochemically Controllable Bistable Rotaxanes | |
| Photochemically Powered Molecular Switches | |
| Conclusions | |
| Diarylethene as a Photoswitching Unit of Intramolecular Magnetic Interaction | |
| Introduction | |
| Photochromic Spin Coupler | |
| Synthesis of Diarylethene Biradicals | |
| Photoswitching Using Bis(3-thienyl)ethene | |
| Reversed Photoswitching Using Bis(2-thienyl)ethene.9 | |
| Table of Contents provided by Publisher. All Rights Reserved. |
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